Synthesis, Structure, and Thermal Behavior of Plumbum-Magnesium Phosphate-Sulfate

被引：1
|
作者：
Pet'kov, V. I. [1 ]
Bokov, A. I. [1 ]
Asabina, E. A. [1 ]
Borovikova, E. Y. [2 ]
机构：
[1] Lobachevsky Natl Res State Univ Nizhny Novgorod, Nizhnii Novgorod 603950, Russia
[2] Moscow MV Lomonosov State Univ, Moscow 119991, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2022年 / 92卷 / 11期
关键词：
plumbum; magnesium; phosphate-sulfate; eulytite structure; phase formation; thermal expansion; EXPANSION; DIFFRACTION; REFINEMENTS;
D O I：
10.1134/S1070363222110172
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A method has been developed for the synthesis of single-phase sulfate-phosphates, which provides keeping from sulfur losses by its binding to sulfate with a high decomposition temperature. The thermally stable sulfate-phosphate Pb2Mg2(PO4)(2)SO4 was studied using X-ray diffraction, IR spectroscopy, DTA, and electron probe microanalysis. According to the results of the study by the Rietveld method, this compound belongs to the eulytite structural type (space group I43d). When the temperature changes, its crystals expand isotropically without polymorphic transitions.
引用
收藏
页码：2334 / 2338
页数：5
相关论文
共 50 条
  • [1] Synthesis, Structure, and Thermal Behavior of Plumbum-Magnesium Phosphate-Sulfate
    V. I. Pet’kov
    A. I. Bokov
    E. A. Asabina
    E. Y. Borovikova
    Russian Journal of General Chemistry, 2022, 92 : 2334 - 2338
  • [2] Synthesis, Crystal Structure, and Thermal Expansion of Sodium Barium Zirconium Phosphate-Sulfate
    Pet'kov, V. I.
    Bokov, A. I.
    Asabina, E. A.
    Lelet, M. I.
    Koval'skii, A. M.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2019, 64 (11) : 1354 - 1358
  • [3] ON THE CRYSTAL-STRUCTURE OF MIXED PHOSPHATE-SULFATE FLUOROAPATITES
    APELLA, MC
    BARAN, EJ
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1981, 36 (05): : 644 - 645
  • [4] SYNTHESIS, CHARACTERIZATION AND APPLICATION IN PEMFC OF ZIRCONIUM OXO PHOSPHATE-SULFATE
    吴宗斌
    于景荣
    刘中民
    田鹏
    杨越
    许磊
    化工学报, 2004, (S1) : 238 - 244
  • [5] Phosphate and sulfate containing inorganic mixture as thermal retardant: synthesis, characterization and thermal behavior
    Rudrarapu, Aravind
    Sahu, Akash Kumar
    Brahma, Gouri Sankhar
    Swain, Trilochan
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2022, 197 (11) : 1170 - 1178
  • [6] Zinc doped calcium phosphate-sulfate hydroxyapatites: Synthesis, characterization, bioactivity, cytotoxicity and antibacterial properties
    Wacharine, Chaima
    Dridi, Atef
    Ben Hassen, Syrine
    Nouri, Faten
    Mosbah, Amor
    Charradi, Khaled
    Trabelsi-Ayadi, Malika
    Ternane, Riadh
    Ceramics International, 2024, 50 (22) : 44773 - 44784
  • [7] Synthesis, Crystal Structure, and Thermal Expansion of Sodium Barium Zirconium Phosphate–Sulfate
    V. I. Pet’kov
    A. I. Bokov
    E. A. Asabina
    M. I. Lelet
    A. M. Koval’skii
    Russian Journal of Inorganic Chemistry, 2019, 64 : 1354 - 1358
  • [8] Investigation of the thermal behavior of magnesium ammonium phosphate hexahydrate
    Ramlogan, Marlon
    Rouff, Ashaki
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 250
  • [9] An investigation of the thermal behavior of magnesium ammonium phosphate hexahydrate
    Marlon V. Ramlogan
    Ashaki A. Rouff
    Journal of Thermal Analysis and Calorimetry, 2016, 123 : 145 - 152
  • [10] An investigation of the thermal behavior of magnesium ammonium phosphate hexahydrate
    Ramlogan, Marlon V.
    Rouff, Ashaki A.
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2016, 123 (01) : 145 - 152
12345