[(2R,3S,5R)-3-Acetoxy-5-(5-formyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-1-yl)-2,3,4,5-tetrahydrofuran-2-yl]methyl acetate

被引:0
|
作者
Jia, Xue-Fei [1 ]
Liu, Nan [1 ]
Fang, Liang-Liang [1 ]
Zhang, Xin-Ying [1 ]
机构
[1] Henan Normal Univ, Sch Chem & Environm Sci, Henan Key Lab Environm Pollut Control, Xinxiang 453007, Henan, Peoples R China
基金
中国国家自然科学基金;
关键词
NUCLEOSIDE;
D O I
10.1107/S1600536811041304
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the two independent but very similar molecules (A and B) of the title compound, C(14)H(16)N(2)O(8), both six-membered pyrimidine rings are nearly planar [maximum deviations = 0.010 (3) angstrom in A and 0.028 (3) angstrom in B]. The five-membered furanose ring in molecule A adopts an envelope conformation, while the same ring in molecule B has a twisted conformation. In the crystal, the A molecules are linked via a pair of intermolecular N-H center dot center dot center dot O hydrogen bonds, forming dimers. Each A molecule is further linked to a B molecule via a second N-H center dot center dot center dot O hydrogen bond. There are also a number of C-H center dot center dot center dot O interactions present, leading to the formation of a three-dimensional network.
引用
收藏
页码:O2951 / U641
页数:14
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