Model for the contamination of fuel cell anode catalyst in the presence of fuel stream impurities

被引:65
|
作者
Zhang, JJ [1 ]
Wang, HJ
Wilkinson, DP
Song, DT
Shen, J
Liu, ZS
机构
[1] Natl Res Council Canada, Inst Fuel Cell Innovat, Vancouver, BC V6T 1W5, Canada
[2] Univ British Columbia, Dept Biol & Chem Engn, Vancouver, BC V6T 1Z4, Canada
关键词
fuel cell; anode catalyst; contamination; modeling;
D O I
10.1016/j.jpowsour.2005.01.013
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A model dealing with the anode catalyst contamination induced by fuel impurities has been developed. This model can be used to describe the transient and steady-state performance losses. Several characteristics such as performance loss, contamination transient time constant and recovery process have also been introduced into the model. The obtained equations can be used to simulate and estimate the chemical and electrochemical reaction rate constants, and make some prediction about the severity of the contamination and the performance recoverability. Crown Copyright (c) 2005 Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:58 / 71
页数:14
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