Reactivity and improved synthesis of aquotris(dimethylsulfoxide)bis(trifluoroacetato)ruthenium(II)

被引：0
|
作者：
Sarkhel, P [1 ]
Rumnong, A
Chakrabarty, S
机构：
[1] St Edmunds Coll, Dept Chem, Shillong 793003, Meghalaya, India
[2] Sankardev Coll, Dept Chem, Shillong 793003, Meghalaya, India
[3] NE Hill Univ, Dept Chem, Shillong 793022, Meghalaya, India
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2005年 / 58卷 / 16期
关键词：
ruthenium(II); trifluoroacetate; dimethylsulfoxide; synthesis; reactivity;
D O I：
10.1080/00958970500241555
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of [Ru(Me2SO)(3)(O2CCF3)(2)(H2O)] with triphenylphosphine and triphenylarsine gives complexes of the type [Ru(Me2SO)(O2CCF3)(2)(EPh3)(2)] (where E = P or As) in which there is a partial substitution of dimethylsulfoxide. Reaction with unidentate N donors resulted in [Ru(O2CCF3)(2)L-4] (where L = pyridine, imidazole, benzimidazole); reaction with diimines yielded [Ru(L-L)(3)](O2CCF3)(2) (where L-L = 2,2'-bipyridyl, 1,10-phenanthroline). All complexes have been characterized by elemental analysis, conductivity measurements, IR and H-1 NMR spectroscopy.
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页码：1499 / 1503
页数：5
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