Palladium-catalyzed cleavage reaction of carbon-carbon triple bond with molecular oxygen promoted by Lewis acid

被引:159
|
作者
Wang, Azhong [1 ]
Jiang, Huanfeng [1 ]
机构
[1] S China Univ Technol, Coll Chem, Guangzhou 510640, Peoples R China
关键词
D O I
10.1021/ja8002217
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new Lewis acid promoted and palladium-catalyzed cleavage reaction of carbon-carbon triple bond with molecular oxygen was reported, in which alkyne or 1.3-diynes is split into carboxylic ester in various alcohols.
引用
收藏
页码:5030 / +
页数:3
相关论文
共 50 条
  • [1] Palladium-catalyzed arylative carbon-carbon bond cleavage of α,α-disubstituted arylmethanols
    Terao, Y
    Wakui, H
    Satoh, T
    Miura, M
    Nomura, M
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (42) : 10407 - 10408
  • [2] Unexpected Base-Promoted Synthesis of Tetrasubstituted Furans via Palladium-Catalyzed Oxidation and Cyclization of Carbon-Carbon Triple Bond with Molecular Oxygen
    Wang, Lianyue
    Li, Jun
    Lv, Ying
    Zhao, Gongda
    Gao, Shuang
    SYNLETT, 2012, (07) : 1074 - 1078
  • [3] Palladium-Catalyzed Carbon-Carbon Bond Formation and Cleavage of Organo(hydro)fullerenes
    Nambo, Masakazu
    Itami, Kenichiro
    CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (19) : 4760 - 4764
  • [4] Palladium-catalyzed synthesis of benzoxazoles by the cleavage reaction of carbon-carbon triple bonds with o-aminophenol
    Xie, Hou-Zhi
    Gao, Qi
    Liang, Ying
    Wang, Heng-Shan
    Pan, Ying-Ming
    GREEN CHEMISTRY, 2014, 16 (04) : 2132 - 2135
  • [5] HOMOGENEOUS, PALLADIUM-CATALYZED, CARBON-CARBON BOND FORMATION
    COLQUHOUN, HM
    CHEMISTRY & INDUSTRY, 1987, (17) : 612 - 617
  • [6] Palladium-Catalyzed Sequential Carbon-Carbon Bond Cleavage/Formation Producing Arylated Benzolactones
    Matsuda, Takanori
    Shigeno, Masanori
    Murakami, Masahiro
    ORGANIC LETTERS, 2008, 10 (22) : 5219 - 5221
  • [7] Palladium-Catalyzed Oxidation and Cyclization of Carbon-Carbon Triple Bonds in Fluorous Media Using Molecular Oxygen
    Wen, Yanmei
    Zhu, Shifa
    Jiang, Huanfeng
    Wang, Azhong
    Chen, Zhenwang
    SYNLETT, 2011, (07) : 1023 - 1027
  • [8] Palladium-Catalyzed Allylic Amination of Homoallylic Alcohols with Amines via Carbon-Carbon Bond Cleavage
    Sun, Gui-Jun
    Wang, Yong
    Kang, Qiang
    SYNTHESIS-STUTTGART, 2015, 47 (19): : 2931 - 2936
  • [9] Lewis acid promoted carbon-carbon bond cleavage of γ-silyloxy-β-hydroxy-α-diazoesters
    Draghici, Cristian
    Brewer, Matthias
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (12) : 3766 - +
  • [10] PALLADIUM-CATALYZED CARBON-CARBON BOND FORMATION IN PYRRLTHALLIUM DERIVATIVES
    MONTI, D
    SLEITER, G
    GAZZETTA CHIMICA ITALIANA, 1994, 124 (03): : 133 - 136