Rotationally resolved photoelectron spectroscopy of autoionizing states of water

被引:13
|
作者
Glab, WL
Child, MS
Pratt, ST
机构
[1] Texas Tech Univ, Dept Phys, Lubbock, TX 79409 USA
[2] Univ Oxford, Dept Theoret Chem, Oxford OX1 3UB, England
[3] Argonne Natl Lab, Argonne, IL 60439 USA
来源
JOURNAL OF CHEMICAL PHYSICS | 1998年 / 109卷 / 08期
关键词
D O I
10.1063/1.476897
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Rotationally resolved photoelectron spectra are reported for rovibronically state-selected autoionizing levels of water. These photoelectron spectra are helpful for the spectroscopic assignment of the autoionizing-levels and provide considerable dynamical information on the mechanisms for the transfer of energy and angular momentum between the ion core and the Rydberg electron. As a result of angular momentum restrictions, photoelectron spectra for J = 0 autoionizing levels provide a direct partial wave analysis for the ejected photoelectrons. (C) 1998 American Institute of Physics. [S0021-9606(98)00832-0].
引用
收藏
页码:3062 / 3068
页数:7
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