Synthesis, crystal structure and bioactivity of a novel linear trinuclear nickel(II) complex

被引:67
|
作者
Luo, Wei
Meng, Xianggao
Sun, Xuzhuo
Xiao, Fengping
Shen, Junfeng
Zhou, Yan
Cheng, Gongzhen [1 ]
Ji, Zhenping
机构
[1] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China
[2] S Cent Univ Natl, Coll Chem & Mat Sci, Wuhan 430074, Peoples R China
基金
中国国家自然科学基金;
关键词
self-assembly; nickel complex; linear trinuclear; antimicrobial activity;
D O I
10.1016/j.inoche.2007.07.022
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A novel linear trinuclear nickel(II) complex, [Ni-3(H2O)(2)(DMA)(2)(acbshz)(2)]center dot 2DMF (DMA = dimethylamine; acbshz = N-acryloyl-5-bromosalicylhydrazide), has been prepared by self-assembly approach. The three nickel atoms arrange in a strictly linear structure, adjacent molecules are linked by intermolecular H bonds to form a 2D infinite wave-like structure. Antibacterial screening data indicate the formation of the trinuclear complex reduced the antimicrobial activity of the ligand. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:1351 / 1354
页数:4
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