Novel method for the preparation of anionic surfactant-selective electrodes

被引:13
|
作者
Varga, I
Mészáros, R
Szakács, Z
Gilányi, T
机构
[1] Eotvos Lorand Univ, Dept Colloid Chem, H-1518 Budapest, Hungary
[2] Eotvos Lorand Univ, Dept Inorgan & Analyt Chem, H-1518 Budapest, Hungary
关键词
D O I
10.1021/la050639m
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A simple one-step synthesis is described for the functionalization of poly(vinyl chloride) used for the preparation of anionic surfactant-selective membrane electrodes. The method is based on the nucleophilic substitution of a fraction of the chlorine atoms bound to the poly(vinyl chloride) backbone by trimethylamine. The prepared slightly charged polymer gave rise to high-quality surfactant-selective electrode membranes, which had a Nernstian response, short response time, and appropriate stability.
引用
收藏
页码:6154 / 6156
页数:3
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