Influence of fluoride additives on the electrical characteristics of alkali silicate electrode glasses

被引：6
|
作者：
Kiprianov, AA [1 ]
Karpukhina, NG [1 ]
机构：
[1] St Petersburg State Univ, Fac Chem, Petrodvorets 198904, Russia
来源：
GLASS PHYSICS AND CHEMISTRY | 2001年 / 27卷 / 01期
基金：
俄罗斯基础研究基金会;
关键词：
Oxide; Polymer; Physical Chemistry; Silicate; Electrical Conductivity;
D O I：
10.1023/A:1009568022611
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
The results of an experimental investigation into the electrical conductivity for series of alkali silicate glasses with fluoride additives are presented. The inference is made concerning the selective fixation of fluorine in tetrahedra created in a glass by the second glass-former oxide with the formation of the strongly acid ionogenic groups [RO3/2F]M--(+). It is found that the ultimate fluorine content in a homogeneous multicomponent glass is determined by the relationship [F, at. %] less than or equal to [R, at. %].
引用
收藏
页码：74 / 79
页数：6
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