Dynamic study on the dispersion of water-soluble catalysts for heavy-oil hydrocracking

被引:3
|
作者
Zhang, Lei [1 ]
Que, Guohe [1 ]
Deng, Wenan [1 ]
机构
[1] Univ Petr, State Key Lab Heavy Oil Proc, Qingdao 266555, Peoples R China
关键词
residue; surfactant; dispersion; dynamics; water-soluble salt; INTERFACIAL-TENSION; ADSORPTION-KINETICS; PHASE-TRANSITIONS; SYSTEMS; DIFFUSION; MODEL; MECHANISMS;
D O I
10.1016/j.petrol.2010.05.004
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The dispersion of water-soluble salts in heavy-oil residues has been analyzed by means of a microscopic image analyzer, and the effectiveness of the dispersion of the water-soluble salts in the residues has been evaluated in terms of the dispersion parameter. A dynamic dispersion model has been built on the basis of a previous model, and the dispersion process of the water-soluble salts in the residues has been studied with respect to time. The results have indicated that the model adequately rationalizes the observed changes in solubility in the different residues: the dispersion parameter of a water-soluble Mo salt shows a temporal change in accordance with a Lorentzian mathematical model in an oil sample designated as Kelamay heavy oil, that of a water-soluble Co salt changes in accordance with a Boltzmann model in a sample designated as Daqing heavy oil, and that of a water-soluble Ni salt changes in accordance with a Gaussian model in Liaohe heavy oil. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:27 / 32
页数:6
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