Photo-catalytic degradation of toxic dye amaranth on TiO2/UV in aqueous suspensions

The photo-catalytic degradation of an azo dye - Amaranth (AM) - has been investigated in TiO2/UV aqueous suspensions. The results obtained from the experiments during H2O2/TiO2 addition show that the highest decolorization rate is provided by the combination of (UV + TiO2 + H2O2). The decolorization efficiencies were 17%, 26%, 38% and 64% in the runs UV, UV + H2O2, UV + TiO2 and (UV + TiO2 + H2O2) after approximately 100 min illumination periods, respectively. The observed dye degradation rates followed pseudo-first order kinetics with respect to the substrate concentration under the experimental conditions used. Different experimental conditions, such as temperature, pH and presence of electron acceptor were investigated. The temperature effect was investigated at the range of 293-313 K and it was observed that decolorization rate increased by the increase in temperature. Chemical oxygen demand and dye absorbance of the photodegraded dye solution substantially decreased. Effect of pH was also investigated and it was observed that the lower the pH the higher the degradation. In addition, an enhancement in the photodegradation rate was observed by the addition of hydrogen peroxide as an electron acceptor. The adsorption trends of Amaranth at various initial concentrations followed the Langmuir isotherm trend. This work adds to the global discussion on the role of the advanced oxidation processes in water treatment. (C) 2011 Elsevier B.V. All rights reserved.