Determination of absolute chirality using resonant X-ray diffraction

被引：10
|
作者：
Tanaka, Y. [1 ]
Lovesey, S. W. [2 ,3 ]
机构：
[1] RIKEN SPring 8 Ctr, Sayo, Hyogo 6795148, Japan
[2] Rutherford Appleton Lab, ISIS Facil, Didcot OX11 0QX, Oxon, England
[3] Diamond Light Source Ltd, Didcot OX11 0QX, Oxon, England
来源：
EUROPEAN PHYSICAL JOURNAL-SPECIAL TOPICS | 2012年 / 208卷 / 01期
关键词：
European Physical Journal Special Topic; Stokes Parameter; Resonant Event; Helicity Beam; Berlinite;
D O I：
10.1140/epjst/e2012-01607-2
中图分类号：
O4 [物理学];
学科分类号：
0702 ;
摘要：
We have demonstrated that resonant diffraction experiments using the circularly polarized X-ray beam absolutely determines the crystal chirality. Both berlinite and quartz crystals belonging to space group P3(2)21 show higher azimuth-constant intensity for the negative (-) helicity beam than that for the the positive (+) helicity beam for space-group forbidden reflection 001. The relation is opposite for quartz crystal belonging to space group P3(1)21. Theoretical calculation shows that this relation completely agrees with the experimental findings for the enantiomorphic space-group pair P3(1)21 and P3(2)21. This method is applicable to chiral motifs that occur in biomolecules, liquid crystals, ferroelectrics, and multiferroics, etc.
引用
收藏
页码：67 / 74
页数：8
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