Crystal structure of Ge4Se9:: a new germanium selenide with Se2 pairs breaking the edge-sharing GeSe4 tetrahedra in GeSe2

被引：18

作者：

Fjellvåg, H ^{[1
]}

Kongshaug, KO ^{[1
]}

Stolen, S ^{[1
]}

机构：

[1] Univ Oslo, Dept Chem, N-0315 Oslo, Norway

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2001年 / Royal Society of Chemistry卷 / 07期

关键词：

D O I：

10.1039/b009794m

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structure of the new germanium selenide Ge4Se9 has been determined by powder X-ray diffraction. It shows a new feature for this class of compounds; corner sharing of tetrahedra via Se-2 dimers with short Se-Se bonds. Structurally, Ge4Se9 is related to GeSe2 in that the edge-sharing tetrahedra in ambient pressure GeSe2 are split by the introduction of Se-2 pairs.

引用

页码：1043 / 1045

页数：3

共 22 条

[1] Structural assignments of NMR chemical shifts in GexSe1-x glasses via first-principles calculations for GeSe2, Ge4Se9, and GeSe crystals
Kibalchenko, Mikhail
Yates, Jonathan R.
Massobrio, Carlo
Pasquarello, Alfredo
PHYSICAL REVIEW B, 2010, 82 (02)
[2] Atomic-scale structure of GeSe2 glass revisited: a continuous or broken network of Ge-(Se1/2)4 tetrahedra?
Petkov, V.
Le Messurier, D.
JOURNAL OF PHYSICS-CONDENSED MATTER, 2010, 22 (11)
[3] EFFECT OF GeSe2 ON THE PREPARATION AND PROPERTIES OF Cu2Zn(Sn,Ge)(S,Se)4 FILMS
Gao, C.
Du, L.
Teng, X.
Yu, W.
CHALCOGENIDE LETTERS, 2018, 15 (08): : 411 - 417
[4] Crystal structures and properties of Eu2GeSe4 and Eu2Ge2Se5
Tampier, M
Johrendt, D
Pöttgen, R
Kotzyba, G
Rosenhahn, C
Mosel, BD
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2002, 57 (02): : 133 - 140
[5] From platinum and [Ge2Se6]4-and [GeSe4]4-precursors to hexagonal mesostructured chalcogenides: Detailed investigation of the solution behavior
Bag, Santanu
Kanatzidis, Mercouri G.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2007, 233 : 79 - 79
[6] Influence of Ge Incorporation from GeSe2 Vapor on the Properties of Cu2ZnSn(S,Se)4 Material and Solar Cells
Gao, Chao
Sun, Yali
Yu, Wei
COATINGS, 2018, 8 (09):
[7] GLASS-FORMATION AND PROPERTIES OF CHALCOGENIDE SYSTEMS .34. NA4GE(SE2)4 AS A MODEL-COMPOUND FOR THE SHORT-RANGE ORDER OF VITREOUS GESE4
FELTZ, A
PFAFF, G
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1985, 69 (2-3) : 425 - 428
[8] Ternary Mn/Ge/Se anions from reactions of [Ba2(H2O)9][GeSe4]:: Synthesis and characterization of compounds containing discrete or polymeric [Mn6Ge4Se17]6- units
Melullis, M
Clerac, R
Dehnen, S
CHEMICAL COMMUNICATIONS, 2005, (48) : 6008 - 6010
[9] Synthesis and Characterization of a New Quaternary Selenide Ba4Sn3GeSe9 Containing [SnGeSe5]4- and [Sn2Se4]4- Units
袁方宇
黄一枝
张浩
周安宜
程文旦
林晨升
Chinese Journal of Structural Chemistry, 2021, 40 (07) : 962 - 966
[10] Synthesis and Characterization of a New Quaternary Selenide Ba4Sn3GeSe9 Containing [SnGeSe5]4- and [Sn2Se4]4- Units
Yuan Fang-Yu
Huang Yi-Zhi
Zhang Hao
Zhou An-Yi
Cheng Wen-Dan
Lin Chen-Sheng
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2021, 40 (07) : 962 - 966

← 1 2 3 →