Direct synthesis of dimethyl carbonate from carbon dioxide and methanol using supported copper (Ni, V, O) catalyst with photo-assistance

被引：70
|
作者：
Wang, X. J.
Xiao, M.
Wang, S. J.
Lu, Y. X.
Meng, Y. Z. [1 ]
机构：
[1] Sun Yat Sen Univ, Inst Optoelect & Funct Composite Mat, State Key Lab Optoelect Mat & Technol, Guangzhou 510275, Peoples R China
[2] Natl Univ Singapore, Off Life Sci, Dept Chem, Singapore 117543, Singapore
[3] Natl Univ Singapore, Off Life Sci, Med Chem Program, Singapore 117543, Singapore
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2007年 / 278卷 / 1-2期
关键词：
photocatalysis; catalysis; carbon dioxide; dimethyl carbonate;
D O I：
10.1016/j.molcata.2007.08.028
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The photo-catalytic effect of a copper modified (Ni, V, O) semiconductor complex catalyst on the direct synthesis of dimethyl carbonate (DMC) from CO, and CH3OH was investigated. The synthesized catalysts were fully characterized by temperature programmed reduction (TPR), X-ray diffraction (XRD). Ultraviolet visible drift reflection spectra (UV-vis DRS) and transmission electron microscopy (TEM). The nano-scale catalyst particles were observed with TEM and light absorbance was then predicted by UV-vis DRS spectra. The pressure and temperature dependencies of the photo-catalytic activity were studied. The results demonstrated that the catalytic activity was enhanced with the assistance of ultraviolet (UV) irradiation compared with the pure thermal and surface catalytic reaction under the same reaction conditions. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码：92 / 96
页数：5
相关论文
共 50 条
  • [1] Cu-Ni/V2O5-SiO2 catalyst for the direct synthesis of dimethyl carbonate from carbon dioxide and methanol
    Zhong, SH
    Li, HS
    Wang, JW
    Xiao, XF
    ACTA PHYSICO-CHIMICA SINICA, 2000, 16 (03) : 226 - 231
  • [2] DIRECT SYNTHESIS OF DIMETHYL CARBONATE FROM SUPERCRITICAL CARBON DIOXIDE AND METHANOL
    Zhao Tiansheng
    催化学报, 1999, (02) : 101 - 102
  • [3] Carbon nanotubes supported Cu-Ni bimetallic catalysts and their properties for the direct synthesis of dimethyl carbonate from methanol and carbon dioxide
    Bian, Jun
    Xiao, Min
    Wang, Shuan-Jin
    Lu, Yi-Xin
    Meng, Yue-Zhong
    APPLIED SURFACE SCIENCE, 2009, 255 (16) : 7188 - 7196
  • [4] The Double Component Catalyst for the Direct Synthesis of Dimethyl Carbonate from Carbon Dioxide, Propylene Oxide and Methanol
    Qi Jiang
    Yie Yang
    Catalysis Letters, 2004, 95 : 127 - 133
  • [5] The double component catalyst for the direct synthesis of dimethyl carbonate from carbon dioxide, propylene oxide and methanol
    Jiang, Q
    Yang, Y
    CATALYSIS LETTERS, 2004, 95 (3-4) : 127 - 133
  • [6] Direct synthesis of dimethyl carbonate from carbon dioxide and methanol catalyzed by base
    Fang, SN
    Fujimoto, K
    APPLIED CATALYSIS A-GENERAL, 1996, 142 (01) : L1 - L3
  • [7] Catalytic developments in the direct dimethyl carbonate synthesis from carbon dioxide and methanol
    Tamboli, Ashif H.
    Chaugule, Avinash A.
    Kim, Hern
    CHEMICAL ENGINEERING JOURNAL, 2017, 323 : 530 - 544
  • [8] Dimethyl carbonate synthesis from carbon dioxide and methanol
    Li, HS
    Zhong, SH
    PROGRESS IN CHEMISTRY, 2002, 14 (05) : 368 - 373
  • [9] Greener synthesis of dimethyl carbonate from carbon dioxide and methanol using a tunable ionic liquid catalyst
    Pawar, Atul A.
    Chaugule, Avinash A.
    Kim, Hern
    OPEN CHEMISTRY, 2019, 17 (01): : 1252 - 1265
  • [10] Study on Cu-Ni/MoO3-SiO2 catalyst for the direct synthesis of dimethyl carbonate from carbon dioxide and methanol
    Zhong, Shunhe
    Li, Hansheng
    Wang, Jianwei
    Xiao, Xiufen
    Shi You Lian Zhi Yu Hua Gong/Petroleum Processing and Petrochemicals, 2000, 31 (06): : 51 - 55
12345