TEMPO-catalyzed oxidation of benzylic alcohols to aldehydes with the H2O2/HBr/ionic liquid [bmim]PF6 system

被引：75
|
作者：
Jiang, N [1 ]
Ragauskas, AJ [1 ]
机构：
[1] Georgia Inst Technol, Sch Chem & Biochem, Atlanta, GA 30332 USA
来源：
TETRAHEDRON LETTERS | 2005年 / 46卷 / 19期
关键词：
TEMPO; alcohol oxidation; benzylic alcohols; ionic liquids; bmim]PF6;
D O I：
10.1016/j.tetlet.2005.03.078
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A selective oxidation of benzylic alcohols to the corresponding alclehydes in room temperature ionic liquid was achieved by using TEMPO/HBr/H2O2 system, and both ether-insoluble acetamido-TEMPO and ionic liquid [bmim]PF6 can be successfully recovered and reused for the oxidation of the same (different) substrate. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码：3323 / 3326
页数：4
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