Simulation Study on Hydrogen-Heating-Power Poly-Generation System based on Solar Driven Supercritical Water Biomass Gasification with Compressed Gas Products as an Energy Storage System

Supercritical water gasification driven by solar energy is a promising way for clean utilization of biomass with high moisture content, but direct discharge of liquid residual causes energy waste and decreases energy efficiency. To reduce energy waste, a poly-generation system for hydrogen-rich gas production coupling heat supply and power generation based on supercritical water gasification of biomass driven by concentrated solar energy was established in this paper, which also provided a novel energy storage method to overcome the shortcomings of solar discontinuity. Thermodynamic model of the system was proposed and life cycle assessment (LCA) of the system was conducted. Influence of different parameters (temperature of 600 degrees C to 800 degrees C, outlet temperature of heat exchanger of 42 degrees C to 56 degrees C, biomass slurry concentration of 5% to 6.5%) on the gasification performance, energy and exergy efficiency, energy distribution and global warming potential (GWP) was discussed. The results indicated that hydrogen yield increased as gasification temperature increased since free radical reaction was enhanced which gas production reaction was classified into. Molar fraction of hydrogen increased as gasification temperature increased and reached 65.6% at 750 degrees C. Energy and exergy efficiency of the system reached 74.84% and 34.87% at 700 degrees C and 600 degrees C respectively and that of gas production was 18.15% at 650 degrees C, which was the highest. Increasing reaction temperature and decreasing biomass slurry concentration were effective ways to decrease GWP. Optimal operating parameter was reaction temperature of 650 degrees C, outlet temperature of heat exchanger of 50 degrees C and biomass concentration of 5%.