Crystal structures of (R,R)-{[Ph(Me)CH]2NLi•pmdeta} and {[PhC(=CH2)NH]Na•pmdeta}2:: alkali metal amides derived from (R,R)-bis(α-methylbenzyl)amine

被引：17

作者：

Andrews, PC ^{[1
]}

Duggan, PJ ^{[1
]}

Maguire, M ^{[1
]}

Nichols, PJ ^{[1
]}

机构：

[1] Monash Univ, Dept Chem, Melbourne, Vic 3800, Australia

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 01期

关键词：

D O I：

10.1039/b007482i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of (BuM)-M-n (M = Li, Na) with [(R,R)]-bis(alpha -methylbenzyl)amine in the presence of pmdeta results in the formation of the chiral lithium amide complex (R,R)-{[Ph(Me)CH](2)NLi . pmdeta} and, remarkably, the sodium enamide, {[PhC(=CH2)NH]Na . pmdeta}(2); both compounds have been authenticated by single crystal X-ray diffraction.

引用

页码：53 / 54

页数：2

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