The separation of the new chiral metal cluster (μ3-Se)RuCoW (CO)8-C5H4C(O)CH3 on an amylopectin tris-(phenylcarbamate) chiral column by HPLC

被引:3
|
作者
Zhou, ZQ [1 ]
Ding, ER [1 ]
Hou, JG [1 ]
Chen, LR [1 ]
Yin, YQ [1 ]
机构
[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China
关键词
D O I
10.1080/10826079808006883
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
The preparation of amylopection tris(phenylcarbamate) (ATP) chiral stationary phases(CSPs) coated on a small-particle (5 mu m, 120 Angstrom) spherical silica support, according to a process that is reported, is presented. A new chiral tetrahedral cluster (mu(3)-Se)RuCoW(CO)(8)C5H4C(O)CH3 2 which was synthesized by the thermal reaction of the precursor (mu(3)-Se)RuCo2(CO)(9) 1 with the functionally substituted cyclopentadienyl tricarbonyl metal complex anions [W(CO)(3)C5B4C(O)CH3](-) is resolved on the amylopectin tris (phenylcarbamate) chiral stationary phases.
引用
收藏
页码:3021 / 3030
页数:10
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