Mono and polynuclear silver(I) complexes with thiosaccharine and triphenylphosphine or 2,2′-bipyridine.: Synthesis, spectroscopic and structural characterization

被引：21

作者：

Dennehy, Mariana

Quinzani, Oscar V.

Jennings, Michael

机构：

[1] Univ Nacl Sur, Dept Quim, RA-8000 Bahia Blanca, Argentina

[2] Univ Western Ontario, Dept Chem, Xray Struct Western, London, ON N6A 5B7, Canada

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2007年 / 841卷 / 1-3期

关键词：

silver(I) complexes; heterocyclic thiones; thiosaccharine; crystal structure;

D O I：

10.1016/j.molstruc.2006.11.071

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Reaction of Ag-6(tsac)(6) (tsac(-) = thiosaccharinate anion) with PPh3 and 2,2 '-bipyridine (bipy) ligands give rise to three new silver-thiosaccharinate complexes, [Ag(tsac)(PPh3)(3)], [Ag-4(tsac)(4)(PPh3)(3)], and [Ag-2(tsac)(2)(bipy)(2)]. Their crystal structures established by single-crystal X-ray diffraction and IR spectroscopic characterizations are reported here. In each complex a singular coordination mode for the thiosaccharinate ligands is observed. The most important features of the different coordination modes of the thionates are discussed. (C) 2006 Elsevier B.V. All rights reserved.

引用

页码：110 / 117

页数：8

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