Development of Iron-Based Rechargeable Batteries with Sintered Porous Iron Electrodes

被引:4
|
作者
Hayashi, Kazushi [1 ]
Maeda, Yasutaka [2 ]
Suzuki, Tsubasa [2 ]
Sakamoto, Hisatoshi [1 ]
Kugimiya, Toshihiro [1 ]
Tan, Wai Kian [2 ]
Kawamura, Go [2 ]
Muto, Hiroyuki [2 ]
Matsuda, Atsunori [2 ]
机构
[1] Kobe Steel Ltd, Elect Res Lab, Kobe, Hyogo 6512271, Japan
[2] Toyohashi Univ Technol, Toyohashi, Aichi 4418580, Japan
关键词
ALKALINE BATTERIES; SECONDARY BATTERY; SULFIDE ADDITIVES; ENERGY-STORAGE; PERFORMANCE;
D O I
10.1149/07518.0111ecst
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
We have developed sintered porous iron negative electrodes used for iron-based rechargeable batteries such as iron-air and nickeliron batteries. The water-atomized iron powders having a diameter of a several tens micrometers were mixed with polyvinyl alcohol that acted as a pore former, and sintered at 1120. degrees C for 20 min in N-2 atmosphere. The iron electrodes were examined for iron-air batteries as well as three electrodes cell. Two distinct plateaus were observed in the discharge curve and the capacity of the iron air batteries exceeded 100 mAh/g(Fe). The proposed electrodes are promising for cost effective, highly safe, and environmental friendly rechargeable batteries.
引用
收藏
页码:111 / 116
页数:6
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