Diaquadiperchlorato[μ-11,23-dimethyl-3,7,15,19-tetraazatricyclo[19.3.1.19,13]hexacosa-1(25),2,7,9,-11,13(26),14,19,21,23-decaene-25,26-diolato-1κ2N,N′;2κ2N",N′";1:2κ2O: O′]dicadmium(II) diaqua[μ-11,23-dimethyl-3,7,15,19-tetraazatricyclo[19.3.1.19,13]hexacosa-1(25), 2,7,9,11,13(26),-14,19,21,23-decaene-25,26-diolato-1κ2N, N′;2κ2N", N′";1:2κ2O:O′]dicadmium(II) diperchlorate

被引：2

作者：

Liu, B

Zhou, H

Pan, ZQ ^{[1
]}

Hu, XL

Chen, L

机构：

[1] Wuhan Inst Chem Technol, Sch Chem Engn & Pharm, Wuhan 430073, Peoples R China

[2] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2005年 / 61卷

关键词：

D O I：

10.1107/S1600536805017599

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title complex, [Cd-2(C24H26N4O2)(ClO4)(2)(H2O)(2)][Cd-2(C24H26N4O2)(H2O)(2)](ClO4)(2), the two distinct macro-cycles adopt essentially flat structures. They each encapsulate two Cd atoms. One Cd coordination polyhedron, completed by a water O atom and a perchlorate O atom, is distorted octahedral, while the other is best described as a CdN2O3 square-based pyramid, with water in the apical site. Both dinuclear complexes are centrosymmetric.

引用

页码：M1295 / M1297

页数：3

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