Electrosynthesis of Cyclic Carbonates From CO2 and Diols in Ionic Liquids Under Mild Conditions

被引：1

作者：

Wang, Huan ^{[1
]}

Wu, La-Xia ^{[1
]}

Lan, Yang-Chun ^{[1
]}

Zhao, Jian-Qing ^{[1
]}

Lu, Jia-Xing ^{[1
]}

机构：

[1] E China Normal Univ, Dept Chem, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China

来源：

INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE | 2011年 / 6卷 / 09期

基金：

中国国家自然科学基金;

关键词：

Carbon dioxide; cyclic carbonates; diols; electrosynthesis; ionic liquids; ORGANIC CARBONATES; ELECTROCHEMICAL ACTIVATION; SILVER CATHODE; DIOXIDE; BMIMBF4; TRANSFORMATION; SOLUBILITY;

D O I：

暂无

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A new electrochemical process for synthesis of cyclic carbonates from CO2 and diols has been tested in CO2-saturated room temperature ionic liquids (RTILs) for the first time. The synthesis has been carried out under mild and safe condition in undivided cell without any additional catalysts. The influence of reaction conditions, such as electrode materials, electrolysis potential, temperature, diol concentration and composition of RTILs, have been investigated. The recyclability of RTILs also has been confirmed. Moreover, the electrochemical reduction behavior has been studied by cyclic voltammetry.

引用

页码：4218 / 4227

页数：10

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