CO2 Separation from Air by Nanoparticle-Supported Liquid Membranes of Amine and Ionic Liquid Mixtures

被引:4
|
作者
Kamiya, Tomoki [1 ]
Kudashewa, Alina [1 ]
Hirota, Yuichiro [1 ]
Ito, Akira [1 ]
机构
[1] Tokyo Inst Technol, Grad Sch Sci & Engn, Dept Chem Engn, Meguro Ku, 2-12-1 Ookayama, Tokyo 1528550, Japan
关键词
Liquid Membrane; Ionic Liquid; Amine; Gas Separation; Carbon Dioxide; FACILITATED TRANSPORT; FLUE-GASES; SURFACE; CAPTURE;
D O I
10.1252/jcej.15we227
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Liquid membranes of triethylenetetramine mixed with ionic liquids were prepared on a hydrophobic microporous membrane using a novel nanoparticle-supported construction. A flat membrane module with the amine/ionic liquid membrane was used for the recovery of CO2 from room air. CO2 was enriched 3-5 times in the sweep air passing through the membrane module. There was an optimum amine/ionic liquid ratio of 10-25 wt% to effectively concentrate the CO2. These permeation results were analyzed in terms of permeability based on a solution-diffusion mechanism. The present membrane process for CO2 separation has proved to be reasonably durable for a greenhouse application.
引用
收藏
页码:607 / 613
页数:7
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