Selective catalytic conversion of biobased carbohydrates to formic acid using molecular oxygen

被引：170
|
作者：
Woelfel, Rene [1 ]
Taccardi, Nicola [1 ]
Boesmann, Andreas [1 ]
Wasserscheid, Peter [1 ]
机构：
[1] Univ Erlangen Nurnberg, Lehrstuhl Chem Reakt Tech, D-91058 Erlangen, Germany
来源：
GREEN CHEMISTRY | 2011年 / 13卷 / 10期
关键词：
HYDROGEN GENERATION; ELECTRON-TRANSFER; DECOMPOSITION; OXIDATION; H5PV2MO10O40; DEGRADATION; ECONOMY; WATER;
D O I：
10.1039/c1gc15434f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new and straightforward method to transform carbohydrate-based biomass to formic acid (FA) by oxidation with molecular oxygen in aqueous solution using a Keggin-type H(5)PV(2)Mo(10)O(40) polyoxometalate as catalyst is presented. Several water-soluble carbohydrates were fully and selectively converted to formic acid and CO(2) under very mild conditions. It is worth noting, even complex biomass mixtures, such as poplar wood sawdust, were transformed to formic acid, giving 19 wt% yield (11% based on the carbon atoms in the feedstock) under non-optimized conditions.
引用
收藏
页码：2759 / 2763
页数：5
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