Styrene-Butadiene Rubber/Halloysite Nanotubes Composites Modified by Epoxidized Natural Rubber

被引:19
|
作者
Jia Zhixin [1 ]
Luo Yuanfang [1 ]
Yang Shuyan [1 ]
Du Mingliang [1 ]
Guo Baochun [1 ]
Jia Demin [1 ]
机构
[1] S China Univ Technol, Coll Mat Sci & Engn, Guangzhou 510640, Guangdong, Peoples R China
关键词
Styrene-Butadiene Rubber; Epoxidized Natural Rubber; Halloysite Nanotubes; Nanocomposites; Modification; HALLOYSITE NANOTUBES; NANOCOMPOSITES; REINFORCEMENT; SILICA;
D O I
10.1166/jnn.2011.4064
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The reinforcement effects of halloysite nanotubes on styrene-butadiene rubber and the modification effect of epoxidized natural rubber on styrene-butadiene rubber/halloysite nanotubes composites were studied. The structure, morphology and properties of styrene-butadiene rubber/halloysite nanotubes composites before and after the incorporation of epoxidized natural rubber were investigated. The results indicated that epoxidized natural rubber can promote the dispersion and orientation of halloysite nanotubes in styrene-butadiene rubber matrix at nanoscale and strengthen interfacial combination between halloysite nanotubes and styrene-butadiene rubber by the formation of covalent bonds and hydrogen bonds between epoxidized natural rubber and halloysite nanotubes. Consequently epoxidized natural rubber can improve the mechanical properties of the vulcanizates of styrene-butadiene rubber/halloysite nanotubes composites. Besides epoxidized natural rubber can decrease the rolling resistance of the vulcanizates and increase the wet grip property of the vulcanizates.
引用
收藏
页码:10958 / 10962
页数:5
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