Removal of trimethylamine in gas by corona-discharge reactor

被引:0
|
作者
Tamon, H [1 ]
Sueoka, Y
Sano, N
Tanthapanichakoon, W
Khongprasarnkaln, P
Charinpanitkul, T
机构
[1] Kyoto Univ, Dept Chem Engn, Kyoto 6068501, Japan
[2] Himeji Inst Technol, Dept Chem Engn, Himeji, Hyogo 6712201, Japan
[3] Chulalongkorn Univ, Dept Chem Engn, Bangkok 10330, Thailand
关键词
gas purification; corona-discharge reactor; electron attachment; removal of trimethylamine; deposition;
D O I
10.1252/jcej.34.1006
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Trimethylamine, one component of malodorous gases from crematory emission, was removed by a corona-discharge reactor to apply the reactor to purification of crematory emission gas. The effects of discharge current and coexisting oxygen or water vapor on the removal efficiency of trimethylamine were investigated. Although trimethylamine was not effectively removed from nitrogen by corona discharge, the removal efficiency was improved greatly by mixing oxygen or water vapor. The amounts of reaction by-products generated were extremely large at high discharge current in the removal from a nitrogen-oxygen mixture. On the other hand, the by-products were greatly suppressed by mixing water vapor. The deposit on the anode of the reactor was analyzed by a thermogravimetry. As a result, trimethylamine was found on the anode surface as the deposit of carbon compounds which have high boiling point.
引用
收藏
页码:1006 / 1011
页数:6
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