Two-Stage Catalytic Process for Producing Unsaturated Esters of Naphthenic Acids in Ionic Liquids

被引：1

作者：

Aliyeva, A. Z. ^{[1
]}

Mamedova, N. A. ^{[2
]}

机构：

[1] Azerbaijan Natl Acad Sci, YH Mammadaliyev Inst Petrochem Proc, Ave Khojaly 30, AZ-1025 Baku, Azerbaijan

[2] Azerbaijan State Oil & Ind Univ, Ave Azadlig 20, AZ-1010 Baku, Azerbaijan

来源：

THEORETICAL AND EXPERIMENTAL CHEMISTRY | 2020年 / 56卷 / 02期

关键词：

synthetic petroleum acids; ionic liquids; multiwalled carbon nanotubes; N-methylpyrrolidone hydrosulfate; allyl and propargyl alcohols;

D O I：

10.1007/s11237-020-09647-1

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An environmentally friendly and cost-effective two-stage catalytic method is developed for the synthesis of unsaturated esters. Naphthenic acids are prerared by catalytic oxidation of a narrow diesel fraction isolated from Balakhan oil on cobalt-containing multiwalled carbon nanotubes mixed with manganese naphthenate. Unsaturated esters are synthesized by subsequent reaction with unsaturated alcohols in the presence of the ionic liquid N-methylpyrrolidone hydrosulfate as an esterification catalyst. The prepared esters are shown to be effective corrosion inhibitors.

引用

页码：136 / 141

页数：6

共 50 条

[1] Two-Stage Catalytic Process for Producing Unsaturated Esters of Naphthenic Acids in Ionic Liquids
A. Z. Aliyeva
N. A. Mamedova
Theoretical and Experimental Chemistry, 2020, 56 : 136 - 141
[2] Evaluation of catalytic activity of two functionalized imidazolium ionic liquids for biodiesel fuel production by a two-stage process
Elsheikh, Yasir A.
Man, Zakaria
Bustam, Azmi
Yusup, Suzana
Akhtar, Faheem H.
Mohamed, I. K.
JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 2014, 89 (07) : 998 - 1006
[3] Producing Fatty Acid Methyl Esters from Free Fatty Acids with Ionic Liquids as Catalyst
Yang, Fangxia
Zhang, Junhua
Guo, Yingjie
Feng, Lele
Wei, Shijun
Chen, Shuai
CHEMICAL ENGINEERING & TECHNOLOGY, 2019, 42 (01) : 174 - 181
[4] Multifunctional two-stage riser fluid catalytic cracking process
Zhang, Jinhong
Shan, Honghong
Chen, Xiaobo
Li, Chunyi
Yang, Chaohe
APPLIED PETROCHEMICAL RESEARCH, 2014, 4 (04): : 395 - 400
[5] Feasibility of producing two-stage (preplaced aggregate) concrete by gravity process
Das, Kunal K.
Lam, Eddie S. S.
STRUCTURAL CONCRETE, 2020, 21 (03) : 1157 - 1163
[6] CATALYTIC METATHESIS OF ESTERS OF UNSATURATED FATTY-ACIDS
VANDAM, PB
MITTELME.MC
BOELHOUW.C
FETTE SEIFEN ANSTRICHMITTEL, 1974, 76 (06): : 264 - 266
[7] Coupling of subcritical methanol with acidic ionic liquids for the acidity reduction of naphthenic acids
Zafar, Faisal
Mandal, Pradip Chandra
Shaari, Ku Zilati Bt Ku
Ullah, Zahoor
POLISH JOURNAL OF CHEMICAL TECHNOLOGY, 2017, 19 (03) : 68 - 74
[8] Removal of Naphthenic Acids from Beijiang Crude Oil by Forming Ionic Liquids
Shi, Lijuan J.
Shen, Benxian X.
Wang, Gongqun Q.
ENERGY & FUELS, 2008, 22 (06) : 4177 - 4181
[9] Stereoselective hydrohalogenation of alkynoic acids and their esters in ionic liquids
Salazar, Jose
Fernandez, Francys
Restrepo, Jelem
Lopez, Simon E.
JOURNAL OF CHEMICAL RESEARCH, 2007, (03) : 170 - 172
[10] Naphthenic acids in oil sands process waters: Identification by conversion of the acids or esters to hydrocarbons
Wilde, Michael J.
Rowland, Steven J.
ORGANIC GEOCHEMISTRY, 2018, 115 : 188 - 196

← 1 2 3 4 5 →