Mossbauer study on characterization of Co[Fe(CN)5NH3]•xH2O

被引：0
|
作者：
Einaga, Y
Gu, ZZ
Kobayashi, Y
Sato, O
Iyoda, T
Ambe, F
Hashimoto, K
Fujishima, A
机构：
[1] Univ Tokyo, Dept Appl Chem, Bunkyo Ku, Tokyo 113, Japan
[2] Inst Phys & Chem Res, Wako, Saitama 35101, Japan
[3] Tokyo Inst Polytech, Kanagawa Acad Sci & Technol, Kanagawa 24302, Japan
[4] Tokyo Metropolitan Univ, Fac Engn, Tokyo 19203, Japan
[5] Univ Tokyo, Adv Sci & Technol Res Ctr, Meguro Ku, Tokyo 153, Japan
来源：
HYPERFINE INTERACTIONS | 1998年 / 116卷 / 1-4期
关键词：
D O I：
10.1023/A:1012698016696
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
The electronic states of Fe atoms in Co[Fe(CN)(5)NH3] . xH(2)O were studied by means of Fe-57 Mossbauer spectroscopy. The Mossbauer spectra of Co[Fe(CN)(5)NH3] . 6H(2)O show the coexistence of mixed valences for the Fe atoms and a magnetic relaxation at 4 K. When water molecules were removed, electron transfer from Co to Fe occurred.
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页码：159 / 166
页数：8
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