The formation of medium-sized rings by the intramolecular cyclization of arylnitrenium ions

被引：12
|
作者：
Abramovitch, RA [1 ]
Miller, J
de Souza, AJC
机构：
[1] Clemson Univ, Dept Chem, Clemson, SC 29634 USA
[2] Univ Estadual Campinas, BR-13100000 Campinas, SP, Brazil
来源：
TETRAHEDRON LETTERS | 2003年 / 44卷 / 36期
关键词：
nitrenium; intramolecular cyclizations; medium-sized rings; MMX;
D O I：
10.1016/S0040-4039(03)01591-0
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The synthesis of an aminodibenzo[a,c]octadiene and an aminodibenzo[a,c]octatriene, guided by molecular mechanics calculations, was effected by the intramolecular cyclization of the corresponding open chain nitrenium ions. Also reported is the predicted failure to synthesize another aminodibenzo[a,c]octadiene using this method. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码：6965 / 6967
页数：3
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