W2Ir2(CO)10(η5-C5H4Me)2

被引:8
|
作者
Lucas, NT [1 ]
Notaras, EGA [1 ]
Humphrey, MG [1 ]
机构
[1] Australian Natl Univ, Dept Chem, Canberra, ACT 0200, Australia
关键词
D O I
10.1107/S1600536801003750
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, decacarbonyl-1 kappa (2) C,2 kappa (2) C,3 kappa (3) C,4 kappa (3) C-bis[1,2(eta (5))-methylcyclopentadienyl]-tetrahedro-ditungstendiiridium, [W2Ir2(C6H7)(2) (CO)(10)], is a mixed-metal cluster with tetrahedral metal-core geometry. The W atoms are each ligated by a eta (5)-methylcyclopentadienyl ligand and two carbonyl ligands, and the Ir atoms are each ligated by three carbonyl ligands.
引用
收藏
页码:M132 / m133
页数:2
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