Reaction of 1-(oxiran-2-ylmethyl)-1H-indole-3-carboxaldehyde with amines

被引：7
|
作者：
Suzdalev, Konstantin F. [1 ]
Den'kina, Sophia V. [1 ]
Starikova, Alena A. [1 ]
Dvurechensky, Vladimir V. [1 ]
Kletsky, Mikhail E. [2 ]
Burov, Oleg N. [2 ]
机构：
[1] So Fed Univ, Inst Phys & Organ Chem, Rostov Na Donu 344006, Russia
[2] So Fed Univ, Dept Chem, Rostov Na Donu 344006, Russia
来源：
MENDELEEV COMMUNICATIONS | 2011年 / 21卷 / 04期
关键词：
D O I：
10.1016/j.mencom.2011.07.021
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Interaction of 1-(oxiran-2-ylmethyl)-1H-indole-3-carboxaldehyde with primary amines occurs at oxirane moiety and leads to beta-aminoalcohols. Quantum-chemical calculations show that these products are more stable than possible alternative Schiff bases arising from aldehyde group of the considered bielectrophiles.
引用
收藏
页码：231 / 233
页数：3
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