Catalytic decarbonylation of biomass-derived carboxylic acids as efficient route to commodity monomers

被引：52
|
作者：
Miranda, Maria O. [1 ]
Pietrangelo, Agostino
Hillmyer, Marc A.
Tolman, William B.
机构：
[1] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA
来源：
GREEN CHEMISTRY | 2012年 / 14卷 / 02期
基金：
美国国家科学基金会;
关键词：
SUCCINIC ACID; CONVERSION; ALKENES;
D O I：
10.1039/C2GC16115J
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The palladium-catalyzed decarbonylation of bio-derived carboxylic acids to alkyl acrylates, styrene, and acrylonitrile is reported. The olefins were isolated by continuous distillation in yields up to 87% by heating a neat, equimolar mixture of pivalic anhydride with the appropriate carboxylic acid to 190 degrees C in the presence of a Pd-phosphine catalyst.
引用
收藏
页码：490 / 494
页数：5
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