Comment on 'Vibrational relaxation and spectral evolution following ultrafast OH stretch excitation of water' by A. Pakoulev, Z. Wang, D.D. Dlott

被引:19
|
作者
Bakker, HJ
Lock, AJ
Madsen, D
机构
[1] FOM, Inst AMOLF, Ultrafast Spectroscopy, NL-1098 SJ Amsterdam, Netherlands
[2] Univ Amsterdam, NL-1018 WS Amsterdam, Netherlands
关键词
D O I
10.1016/j.cplett.2003.12.079
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In a recent Letter by Pakoulev et al. [CPL 371 (2003) 594], time-resolved anti-Stokes Raman measurements of the spectral evolution and relaxation of the OH stretch vibrations of pure H2O were presented. These measurements led the authors to reinterpret the results of previous femtosecond mid-infrared pump-probe studies on water. Here we show that this reinterpretation is incorrect. (C) 2003 Elsevier B.V. All rights reserved.
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页码:329 / 331
页数:3
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