Concerning the ring-opening polymerization of lactide and cyclic esters by coordination metal catalysts

被引：77
|
作者：
Chisholm, Malcolm H. [1 ]
机构：
[1] Ohio State Univ, Dept Chem, Columbus, OH 43210 USA
来源：
PURE AND APPLIED CHEMISTRY | 2010年 / 82卷 / 08期
关键词：
biodegradability; cyclic esters; metal-alkoxides; polyesters; ring-opening polymerization; ORGANIC CATALYSTS; RAC-LACTIDE; LIVING POLYMERIZATION; ALKOXIDE INITIATORS; COMPLEXES; POLYLACTIDE; CHEMISTRY; MAGNESIUM; LIGAND; ZINC;
D O I：
10.1351/PAC-CON-09-09-24
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A summary of the reactions involved in the ring-opening polymerization (ROP) of lactide (LA) to give polylactides (PLAs) is presented along with competing reactions. Particular attention is given to the stereoselective polymerization of rac-LA to give heterotactic PLA and mesa-LA to give syndiotactic PLA by aluminum Schiff-based catalysts and to the development of highly active group 2 metal single-site catalysts. Melt or solvent-free polymerization is also described along with reactions that lead exclusively to cyclic-polylactides.
引用
收藏
页码：1647 / 1662
页数：16
相关论文
共 50 条
  • [1] β-Diketiminate and β-Ketoiminate Metal Catalysts for Ring-Opening Polymerization of Cyclic Esters
    Gloeckler, Eduard
    Ghosh, Swarup
    Schulz, Stephan
    [J]. POLYMER REVIEWS, 2023, 63 (02) : 478 - 514
  • [2] Advanced Catalysts in Ring-Opening Polymerization of Cyclic Esters
    Wu, Jincai
    Chen, Hsuan-Ying
    Hormnirun, Pimpa
    [J]. FRONTIERS IN CHEMISTRY, 2019, 7
  • [3] Rare-earth metal complexes as catalysts for ring-opening polymerization of cyclic esters
    Lyubov, Dmitry M.
    Tolpygin, Aleksey O.
    Trifonov, Alexander A.
    [J]. COORDINATION CHEMISTRY REVIEWS, 2019, 392 : 83 - 145
  • [4] INOR 852-New catalysts for ring-opening polymerization and ring-enlargement of lactide and related cyclic esters
    Chisholm, Malcolm H.
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2008, 235
  • [5] Controlled ring-opening polymerization of cyclic esters with phosphoric acid as catalysts
    Zhou, Xi
    Hong, Liangzhi
    [J]. COLLOID AND POLYMER SCIENCE, 2013, 291 (09) : 2155 - 2162
  • [6] Controlled ring-opening polymerization of cyclic esters with phosphoric acid as catalysts
    Xi Zhou
    Liangzhi Hong
    [J]. Colloid and Polymer Science, 2013, 291 : 2155 - 2162
  • [7] Guanidine and amidine catalysts for controlled ring-opening polymerization of cyclic esters
    Pratt, Russell C.
    Long, David A.
    Lohmeijer, Bas G. G.
    Waymouth, Robert M.
    Hedrick, James L.
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 231
  • [8] Alkali and Alkaline Earth Metal Complexes as Versatile Catalysts for Ring-Opening Polymerization of Cyclic Esters
    Bhattacharjee, Jayeeta
    Sarkar, Alok
    Panda, Tarun K.
    [J]. CHEMICAL RECORD, 2021, 21 (08): : 1898 - 1911
  • [9] Ring-opening polymerization of cyclic esters by cyclodextrins
    Harada, Akira
    Osaki, Motofumi
    Takashima, Yoshinori
    Yamaguchi, Hiroyasu
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2008, 41 (09) : 1143 - 1152
  • [10] Cerium(IV) Catalysts for the Ring-Opening Polymerization of Lactide
    Broderick, Erin M.
    Diaconescu, Paula L.
    [J]. INORGANIC CHEMISTRY, 2009, 48 (11) : 4701 - 4706
12345