Synthesis and characterization of Na2{Ge(C6H3-2,6-Trip2)}2 and K2{Sn(C6H3-2,6-Trip2)}2 (Trip = -C6H2-2,4,6-i-Pr3):: A new class of multiply bonded main group compounds

被引：61

作者：

Pu, LH

Senge, MO

Olmstead, MM

Power, PP ^{[1
]}

机构：

[1] Univ Calif Davis, Dept Chem, Livermore, CA 95616 USA

[2] Free Univ Berlin, Inst Organ Chem, D-14195 Berlin, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1998年 / 120卷 / 48期

关键词：

D O I：

10.1021/ja982717g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：12682 / 12683

页数：2

共 50 条

[1] Synthesis and characterization of Na2{Ge(C6H3-2,6-trip2)}2 and K2{Sn(C6H3-2,6-trip2)}2 (trip = -C6H2-2,4,6-i-Pr3): A new class of multiply bonded main group compounds
J Am Chem Soc, 48 (12682):
[2] Synthesis and characterization of the monomeric terphenyl metal halides Ge(Cl){C6H3-2,6-Trip2} (Trip = C6H2-2,4,6-i-Pr3) and Sn(I){C6H3-2,6-Trip2} and the terphenyl metal amide Sn{N(SiMe3)2}{C6H3-2,6-Trip2}
Pu, LH
Olmstead, MM
Power, PP
Schiemenz, B
ORGANOMETALLICS, 1998, 17 (26) : 5602 - 5606
[3] Characterization of the sterically encumbered terphenyl-substituted species 2,6-Trip2H3C6Sn-Sn(Me)2C6H3-2,6-Trip2, an unsymmetric, group 14 element, methylmethylene, valence isomer of an alkene, its related lithium derivative 2,6-Trip2H3C6(Me)2Sn-Sn(Li)(Me)C6H3-2,6-Trip2, and the monomer Sn(t-Bu)C6H3-2,6-Trip2 (Trip = C6H2-2,4,6-i-Pr3)
Eichler, BE
Power, PP
INORGANIC CHEMISTRY, 2000, 39 (24) : 5444 - 5449
[4] Isolation and structural characterization of the lithium cyanoorganocuprate salt [Li(THF)2{Cu(CN)C6H3-2,6-Trip2}]2 (Trip = -C6H2-2,4,6-i-Pr3)
Hwang, CS
Power, PP
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (25) : 6409 - 6410
[5] Terphenyl ligand stabilized lead(II) derivatives of simple organic groups:: Characterization of Pb(R)C6H3-2,6-Trip2 (R = Me, t-Bu, or Ph; Trip = C6H2-2,4,6-i-Pr3), {Pb(μ-Br)C6H3-2,6-Trip2}2, py•Pb(Br)C6H3-2,6-Trip2 (py = pyridine), and the bridged plumbylyne complex [{W(CO)4}2(μ-Br)(μ-PbC6H3-2,6-Trip2)]
Pu, LH
Twamley, B
Power, PP
ORGANOMETALLICS, 2000, 19 (15) : 2874 - 2881
[6] Synthesis and characterization of 2,6-Trip2H3C6PbPbC6H3-2,6-Trip2 (Trip C6H2-2,4,6-i-Pr3):: A stable heavier group 14 element analogue of an alkyne
Pu, LH
Twamley, B
Power, PP
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (14) : 3524 - 3525
[7] Synthesis and characterization of the very bulky phenols Ar*OH and Ar′OH (Ar* = C6H3-2,6-Trip2, Trip = C6H2-2,4,6-iPr3; Ar′ = C6H3-2,6-Dipp2, Dipp = C6H3-2,6-iPr2) and their lithium and sodium derivatives (LiOAr′)2 and (NaOAr*)2
Stanciu, C
Olmstead, MM
Phillips, AD
Stender, M
Power, PP
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2003, (18) : 3495 - 3500
[8] Models for Bonding in the Alkali Metal-Gallium Clusters K2Ga4(C6H3-2,6-Trip2)2 and Na2Ga4Trip6 (Trip=C6H2-2,4,6-i-Pr3): Importance of Alkali Metal-Aryl Interactions
Andrew D. Phillips
Philip P. Power
Journal of Cluster Science, 2002, 13 : 569 - 586
[9] Models for bonding in the alkali metal-gallium clusters K2Ga4(C6H3-2,6-Trip2)2 and Na2Ga4Trip6 (Trip = C6H2-2,4,6-i-Pr3):: Importance of alkali metal-aryl interactions
Phillips, AD
Power, PP
JOURNAL OF CLUSTER SCIENCE, 2002, 13 (04) : 569 - 586
[10] [2,6-Trip2H3C6Sn(μ-H)]2 (Trip = C6H2-2,4,6-i-Pr3):: Synthesis and structure of a divalent group 14 element hydride
Eichler, BE
Power, PP
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (36) : 8785 - 8786

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