Hydrogen storage in carbon nanostructures via spillover

被引：99
|
作者：
Pyle, Darryl S. [1 ]
Gray, E. MacA. [1 ]
Webb, C. J. [1 ]
机构：
[1] Griffith Univ, Queensland Micro & Nanotechnol Ctr, Brisbane, Qld 4111, Australia
来源：
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2016年 / 41卷 / 42期
关键词：
Hydrogen storage; Carbon nanostructures; Spillover; Surface functionalization; NITROGEN-DOPED GRAPHENE; HIGH-SURFACE-AREA; ACTIVATED CARBON; ATOMIC-HYDROGEN; PLATINUM NANOPARTICLES; ADSORPTION PROPERTIES; EXFOLIATED GRAPHENE; MOLECULAR-HYDROGEN; CRYSTAL-SURFACES; PD NANOPARTICLES;
D O I：
10.1016/j.ijhydene.2016.08.061
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The addition of transition metal nanoparticles to carbon nanostructures has been shown to increase the hydrogen storage capacity of carbon nanostructures by dissociating molecular hydrogen and allowing adsorption via chemical means, a process known as hydrogen spillover. This paper is an overview of experimental and theoretical studies on hydrogen storage on transition metal doped carbon nanostructures via the spillover mechanism and the prospects for achieving practical hydrogen storage targets. The most promising materials are found to be high surface area hexagonal system carbons for which the pi-conjugation is broken by well dispersed oxygen functional groups or lattice dopants. Crown Copyright (C) 2016 Published by Elsevier Ltd on behalf of Hydrogen Energy Publications LLC. All rights reserved.
引用
收藏
页码：19098 / 19113
页数：16
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