Effect of Water Molecules on Structure and Properties of Metal-Organic Frameworks

被引：0
|
作者：
Zhang Zhuo-Ming [1 ]
Yang Jiang-Feng [1 ]
Wang Yong [1 ]
Li Jin-Ping [1 ]
机构：
[1] Taiyuan Univ Technol, Res Inst Fine Chem, Taiyuan 030024, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2015年 / 31卷 / 04期
关键词：
metal-organic frameworks(MOFs); hydrolysis; adsorbed; water molecules; HYDROGEN STORAGE; SURFACE-AREA; STABILITY; ADSORPTION; DESIGN; RECOMMENDATIONS; NETWORKS; SITES;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Metal-organic frameworks (MOFs) is a new class of organic-inorganic hybrids. MOFs have exhibited the attractive prospects in many fields, such as the gas adsorption and separation, the catalysts, the magnetism and the bio-medicine. However, its performance will be greatly affected in the humid environment, which hindered its industrialization process. Firstly, this paper describes the destruction mechanism of MOFs at the presence of water molecules, and we summarize the elements of MOFs structure stability at the presence of water based on their two structural elements; And then, this paper summarizes the adsorption mechanism of water molecules on MOFs and the influence of it; Finally, we made a prospect of the MOF-water issue in order to provide a reference for future research.
引用
收藏
页码：627 / 634
页数：8
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