6-Dimethylaminopentafulvene as a Lewis Base Component in Frustrated Lewis Pairs: Reversible Carbon-Carbon Coupling in FLP Chemistry

被引：11
|
作者：
Xu, Bao-Hua [1 ]
Kehr, Gerald [1 ]
Froehlich, Roland [1 ]
Erker, Gerhard [1 ]
机构：
[1] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany
来源：
ORGANOMETALLICS | 2011年 / 30卷 / 19期
关键词：
HETEROLYTIC DIHYDROGEN ACTIVATION; BOND ACTIVATION; C-H; BORANE; HYDROGENATION; CO2; 1,1-CARBOBORATION; PHOSPHINES; REDUCTION; COMPLEXES;
D O I：
10.1021/om200818x
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The strongly electrophilic boranes RB(C6F5)(2) form frustrated Lewis pairs with an aminofulvene derivative. The new C/B FLPs undergo typical cooperative 1,2-addition reactions to alkynes with carbon-carbon bond formation.
引用
收藏
页码：5080 / 5083
页数：4
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