Direct one-pot reductive imination of nitroarenes using aldehydes and carbon monoxide by titania supported gold nanoparticles at room temperature

被引:49
|
作者
Huang, Jun [1 ]
Yu, Lei [1 ]
He, Lin [1 ]
Liu, Yong-Mei [1 ]
Cao, Yong [1 ]
Fan, Kang-Nian [1 ]
机构
[1] Fudan Univ, Dept Chem, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China
基金
中国国家自然科学基金;
关键词
NITRO-COMPOUNDS; CHEMOSELECTIVE HYDROGENATION; SECONDARY-AMINES; EFFICIENT CATALYST; AEROBIC OXIDATION; ENHANCED ACTIVITY; IMINES; CO; ALCOHOLS; NITROAROMATICS;
D O I
10.1039/c1gc15307b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The direct one-pot reductive imination of nitroarenes with various aldehydes by a titania supported gold catalyst at room temperature using CO/H2O as a reducing agent is illustrated. This method is simple, economic, general and environmentally benign, thus resulting in practical advantages for the synthesis of imines and their derivatives.
引用
收藏
页码:2672 / 2677
页数:6
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