Frontal atom transfer radical polymerization of tri(ethylene glycol) dimethacrylate

被引：0
|
作者：
Bidali, S
Fiori, S
Malucelli, G
Mariani, A
机构：
[1] Univ Sassari, Dipartimento Chim, I-07100 Sassari, Italy
[2] Univ Sassari, Local INSTM Res Unit, I-07100 Sassari, Italy
[3] Politecn Torino, Dipartimento Sci Mat & Ingn Chim, I-10129 Turin, Italy
[4] Politecn Torino, Local INSTM Res Unit, I-10129 Turin, Italy
来源：
E-POLYMERS | 2003年
关键词：
D O I：
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中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The first frontal atom transfer radical polymerization (FATRP) has been successfully carried out using tri(ethylene glycol) dimethacrylate as a monomer. The effect of the catalyst/initiator ratio has been investigated and related to the front velocity and its maximum temperature. By comparing this new approach with classical radical polymerization routes and with conventional frontal polymerization, it was found that the so-obtained polymer is characterized by higher conversion, shorter reaction times, higher degradation temperature, and does not contain entrapped bubbles.
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页数：12
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