Boron Trifluoride Gas Adsorption in Metal-Organic Frameworks

被引：14

作者：

Siu, Paul W. ^{[1
]}

Siefried, John P. ^{[1
]}

Weston, Mitchell H. ^{[1
]}

Fuller, Patrick E. ^{[1
]}

Morris, William ^{[1
]}

Murdock, Christopher R. ^{[1
]}

Hoover, William J. ^{[1
]}

Richardson, Rachelle K. ^{[1
]}

Rodriguez, Stephanie ^{[1
]}

Farha, Omar K. ^{[1
,2
,3
,4
]}

机构：

[1] NuMat Technol, 8025 Lamon Ave, Skokie, IL 60077 USA

[2] Northwestern Univ, Dept Chem, 2145 Sheridan Rd, Evanston, IL 60208 USA

[3] Northwestern Univ, Int Inst Nanotechnol, 2145 Sheridan Rd, Evanston, IL 60208 USA

[4] King Abdulaziz Univ, Fac Sci, Dept Chem, Jeddah 21589, Saudi Arabia

来源：

INORGANIC CHEMISTRY | 2016年 / 55卷 / 23期

基金：

美国国家科学基金会;

关键词：

H-2; SORPTION;

D O I：

10.1021/acs.inorgchem.6b02273

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Coordinatively unsaturated metal organic frameworks (MOFs) were studied for boron trifluoride (BF3) sorption. MOF-74-Mg, MOF-74-Mn, and MOF-74-Cu show high initial uptake (below 6.7 X 10(-3) bar) with negligible deliverable capacity. The BF3 isotherm of MOF-74-Cu exhibits gradual uptake up to 0.9 bar and has a deliverable gravimetric capacity that is more than 100% higher than activated carbon. Two other Cu2+ MOFs, MOF-SOS and HKUST-1, have slightly lower deliverable capacities compared to MOF-74-Cu.

引用

页码：12110 / 12113

页数：4

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