3-(5-Nitro-2-furyl)-1-phenylprop-2-yn-1-one

被引:1
|
作者
Fun, Hoong-Kun [1 ]
Quah, Ching Kheng [1 ]
Nithinchandra [2 ]
Kalluraya, Balakrishna [2 ]
机构
[1] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, Usm 11800, Penang, Malaysia
[2] Mangalore Univ, Dept Studies Chem, Mangalore 574199, India
关键词
X-RAY; DIFFRACTION;
D O I
10.1107/S1600536810043850
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C13H7NO4, the 2-furyl ring is essentially planar, with a maximum deviation of 0.004 (1) angstrom. It is inclined at an angle of 11.69 (4)degrees to the benzene ring. The nitro group is slightly twisted out of the plane of the 2-furyl ring, with a dihedral angle of 5.72 (8)degrees. There is a short O center dot center dot center dot C contact of 2.8562 (8) angstrom (symmetry code: -x, -y, 2 - z). In the crystal packing, molecules are linked via a pair of intermolecular C-H center dot center dot center dot O hydrogen bonds, giving rise to an R-2(2)(10) ring motif. Molecules are further linked into two-dimensional networks parallel to [100] via other intermolecular C-H center dot center dot center dot O hydrogen bonds. The crystal structure is consolidated by C-H center dot center dot center dot pi interactions.
引用
收藏
页码:O3031 / U2031
页数:10
相关论文
共 50 条
  • [1] LDA-mediated domino carbolithiation reactions of vinylidenecyclopropanes with but-3-yn-2-one and 1-phenylprop-2-yn-1-one
    Lu, Bei-Li
    Lu, Jian-Mei
    Shi, Min
    TETRAHEDRON LETTERS, 2010, 51 (02) : 321 - 324
  • [2] 2,3-Dibromo-1-(4-chlorophenyl)-3-(5-nitro-2-furyl)propan-1-one
    Fun, Hoong-Kun
    Yeap, Chin Sing
    Shetty, Shobhitha
    Kalluraya, Balakrishna
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O3220 - U1096
  • [3] Prop-2-yn-1-als and 1-phenylprop-2-yn-1-one in the chalcogen Baylis-Hillman reaction
    Medvedeva, AS
    Demina, MM
    Novopashin, PS
    Sarapulova, GI
    Afonin, AV
    MENDELEEV COMMUNICATIONS, 2002, (03) : 110 - 111
  • [4] 2,3-Dibromo-3-( 5-nitro-2-furyl)-1-phenylpropan-1-one
    Shahani, Tara
    Fun, Hoong-Kun
    Nithinchandra
    Kalluraya, Balakrishna
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O546 - U1074
  • [5] Crystal structure of 3-(4-methoxyphenyl)-1-phenylprop-2-yn-1-one, C16H12O2
    Smit, Jireh B. M.
    Marais, Charlene
    Malan, Frederick P.
    Bezuidenhout, Barend C. B.
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2019, 234 (02): : 359 - 360
  • [6] ZUR SYNTHESE VON 3-(5-NITRO-2-FURYL)PROPIOLSAURE
    KAI, F
    OGAWA, H
    CHEMICAL & PHARMACEUTICAL BULLETIN, 1963, 11 (09) : 1205 - +
  • [7] MASS-SPECTRAL FRAGMENTATION OF "3-(5-NITRO-2-FURYL)-1,2,4-TRIAZOLES
    KATO, Y
    HIRAO, I
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1972, 45 (06) : 1876 - +
  • [8] [3-(5-Nitro-2-furyl)-1-phenyl-1H-pyrazol-4-yl](phenyl)methanone
    Goh, Jia Hao
    Fun, Hoong-Kun
    Nithinchandra
    Kalluraya, B.
    Rai, N. Satheesh
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O1229 - U1366
  • [9] FURAN-DERIVATIVES .135. ANHYDRIDES OF 3-(5-NITRO-2-FURYL)ACRYLIC ACID AS STARTING MATERIALS FOR THE SYNTHESIS OF 1-(5-NITRO-2-FURYL)-2-(1,3,4-OXADIAZOL-2-YL)ETHENES
    POVAZANEC, F
    KOVAC, J
    CHEMICKE ZVESTI, 1979, 33 (06): : 798 - 802
  • [10] SYNTHESIS OF SOME 1-(5-NITRO-2-FURYL)-3-PHENYL-2-PROPEN-1-ONE AND THEIR BROMO DERIVATIVES
    TULECKI, J
    SOBIAK, S
    POLISH JOURNAL OF CHEMISTRY, 1982, 56 (10-1) : 1559 - 1562