Synthesis, crystal structure and third-order Nonlinear optical properties of a cobalt(III) three-dimensional supramolecular compound

被引：0
|
作者：
Zhang, Z. X.
Li, Y. [1 ]
Li, K. C.
Song, W. D.
Li, Q. S.
机构：
[1] Guangdong Ocean Univ, Coll Sci, Zhanjiang 524088, Peoples R China
[2] Jilin Univ, Coll Chem, Changchun 130023, Peoples R China
[3] Jilin Univ, Coll Phys, Changchun 130023, Peoples R China
来源：
POLISH JOURNAL OF CHEMISTRY | 2007年 / 81卷 / 10期
关键词：
cobalt(III) complex; supramolecular compound; third-orderNLO behavior;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Acobalt(Ill) 8-hydroxyquinoline complex [Co(8-Q)(3)]-0.5CH(3)OH 1, (8-HQ = 8-hydroxyquinoline) has been synthesized by low-temperature solid-state reaction. Single crystal X-ray analyses revealed that compound 1 possesses a three-dimensional (3-D) supramolecular structure. Each Co ion is bridged by three 8-hydroxyquinoline ligands. The compound 1 was characterized by elemental analysis, IR spectra and UV-visible spectra. The third-order nonlinear optical (NLO) properties were also investigated and they exhibit good nonlinear absorption and self-defocusing performance with modulus of the hyper-polarizability (gamma) 5.23x10(-30) esu for 1 in a 1.06x10(-4) mol-dm(-3) DMF solution.
引用
收藏
页码：1707 / 1716
页数：10
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