Structure and chemical valence study of Srn+1RunO3n+1 (n=1, 2, ∞) series

被引：2
|
作者：
Zheng Long [1 ]
Zhu Xiao-Qin [1 ]
Sui Yong-Xing [1 ]
Xue Jian-Zhong [1 ]
Liu Bo [1 ]
Pei Ming-Xu [1 ]
机构：
[1] Jiangsu Univ Technol, Sch Math & Phys, Changzhou 213001, Peoples R China
来源：
CHINESE PHYSICS B | 2015年 / 24卷 / 05期
关键词：
ruthenates; structure parameter; x-ray diffraction; extended x-ray absorption fine structure;
D O I：
10.1088/1674-1056/24/5/056101
中图分类号：
O4 [物理学];
学科分类号：
0702 ;
摘要：
Effect of structure parameter n and its coupling with the connection mode among RuO6 octahedra of Srn+1RunO3n+1 (n = 1, 2, infinity) are investigated. The gradually enhanced rotation and tilting effect with increasing n are observed in Srn+1RunO3n+1. Besides, the chemical valence of Ru is not changed, while the one of Sr gradually varies with increasing n, which highlights the great contribution of connection mode to the chemical environment. Our results show a strong n dependence on the connection mode between octahedra in Srn+1RunO3n+1 (n = 1, 2, infinity).
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页数：5
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