Cu5(VO4)2(OH)4•H2O nanobelts as anode materials for lithium-ion batteries

被引:14
|
作者
Zhang, Shaoyan [1 ]
An, Wei [2 ]
Wu, Ge [1 ]
机构
[1] Shijiazhuang Univ, Coll Chem Engn, Shijiazhuang 050035, Hebei Province, Peoples R China
[2] Sinochem Hebei Corp, Fine Chem Business Dept, Shijiazhuang 050035, Hebei Province, Peoples R China
基金
中国国家自然科学基金;
关键词
RECHARGEABLE LI BATTERIES; HIGH-PERFORMANCE ANODE; HYDROTHERMAL SYNTHESIS; HOLLOW MICROSPHERES; POSITIVE ELECTRODE; SECONDARY BATTERY; CAPACITY; NANOSHEETS; VANADATES;
D O I
10.1016/j.cplett.2014.12.047
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The Cu-5(VO4)(2)(OH)(4)center dot H2O nanobelts with widths of 100 nm, thicknesses of 50 nm, and lengths up to about 500 nm have been successfully prepared on a large scale via a hydrothermal technique. Electrochemical measurements revealed that the as-prepared Cu-5(VO4)(2)(OH)(4)center dot H2O nanobelts exhibited higher specific capacity (534.8 mAh g(-1) at 50 mA g(-1)), high Coulombic efficiency, and good cycle stability, indicating a promising anode candidate for the application in lithium-ion batteries. Significantly, this is the first report on the Cu-5(VO4)(2)(OH)(4)center dot H2O as anode materials in lithium-ion batteries, and the present work will greatly expand the range of anode choices in lithium-ion batteries. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:1 / 4
页数:4
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