Uranium(VI) coordination polymers with pyromellitate ligand: Unique 1D channel structures and diverse fluorescence

被引：30
|
作者：
Zhang, Yingjie [1 ]
Bhadbhade, Mohan [2 ]
Karatchevtseva, Inna [1 ]
Price, Jason R. [3 ]
Liu, Hao [4 ]
Zhang, Zhaoming [1 ]
Kong, Linggen [1 ]
Cejka, Jiri [5 ]
Lu, Kim [1 ]
Lumpkin, Gregory R. [1 ]
机构：
[1] Australian Nucl Sci & Technol Org, Kirrawee Dc, NSW 2232, Australia
[2] Univ New S Wales, Mark Wainwright Analyt Ctr, Kensington, NSW 2052, Australia
[3] Australian Synchrotron, Clayton, Vic 3168, Australia
[4] Univ Technol Sydney, Sch Chem & Forens Sci, Ctr Clean Energy Technol, Sydney, NSW 2007, Australia
[5] Natl Museum, Dept Mineral, CZ-11579 Prague 1, Czech Republic
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2015年 / 226卷
关键词：
Uranium(VI); Pyromellitate; Complex; Raman spectroscopy; Fluorescence; CRYSTAL-STRUCTURE; MAGNETIC-PROPERTIES; DIMETHYL-SULFOXIDE; RAMAN-SPECTROSCOPY; ACID; FRAMEWORKS; COMPLEXES; COBALT(II); MOLECULES; PHOSPHATE;
D O I：
10.1016/j.jssc.2015.01.033
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three new coordination polymers of uranium(VI) with pyromellitic acid (H(4)btca) have been synthesized and structurally characterized. (ED)[(UO2)(btca)]center dot(DMSO)center dot 3H(2)O (1) (ED=ethylenediammonium; DMSO=dimethylsulfoxide) has a lamellar structure with intercalation of ED and DMSO. (NH4)(2)[(UO2)(6)O-2(OH)(6)(btca)]center dot similar to 6H(2)O (2) has a 3D framework built from 7-fold coordinated uranyl trinuclear units and btca ligands with 1D diamond-shaped channels (similar to 8.5 angstrom x similar to 8.6 angstrom). [(UO2)(2)(H2O)(btca)]center dot 4H(2)O (3) has a 3D network constructed by two types of 7-fold coordinated uranium polyhedron. The unique mu(5)-coordination mode of btca in 3 enables the formation of 1D olive-shaped large channels (similar to 4.5 angstrom x similar to 19 angstrom). Vibrational modes, thermal stabilities and fluorescence properties have been investigated. Crown Copyright (C) 2015 Published by Elsevier Inc. All rights reserved.
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页码：42 / 49
页数：8
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