Hydrofunctionalization of alkenes promoted by diruthenium complexes [{(η5-C5H3)2(SiMe2)2}Ru2(CO)3(η2-CH2=CH-R)(μ-H)]+ featuring a kinetically inert proton on a metal-metal bond

被引：23

作者：

Ovchinnikov, MV ^{[1
]}

LeBlanc, E ^{[1
]}

Guzei, IA ^{[1
]}

Angelici, RJ ^{[1
]}

机构：

[1] Iowa State Univ, Dept Chem, Ames, IA 50011 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2001年 / 123卷 / 46期

关键词：

D O I：

10.1021/ja0116573

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

No abstract available

引用

页码：11494 / 11495

页数：2

共 50 条

[1] A kinetically inert proton on a metal-metal bond in [{(η5-C5H3)2(SiMe2)2}Ru2(CO)4(μ-H)]+ that promotes reactions with amines
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[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (25) : 6130 - 6131
[2] Reactions of the protonated dinuclear ruthenium complex [{(η5-C5H3)2(SiMe2)2}Ru2(CO)4(μ-H)]+ with nucleophiles
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[3] Amine attack on the carbonyl ligands of the protonated dicyclopentadienyl-bridged diruthenium complex [{(η5-C5H3)2(SiMe2)2}Ru2(CO)4(μ-H)]+
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[9] Stereoselective synthesis and reactivity of cis- and trans-dimolybdenum nitrosyl derivatives with the bridging bis(dimethylsilanediyl)di(η5-cyclopentadienyl) ligand.: X-ray molecular structures of cis-[{Mo(CO)2(NO)}2{μ-(η5-C5H3)2(SiMe2)2}], trans-[{Mo(CO)(NO)(CNtBu)}2{μ-(η5-C5H3)2(SiMe2)2}], cis-[{Mo2(CO)3(NO)2(PMe3)}{μ-(η5-C5H3)2(SiMe2)2}] and trans-[{Mo(NO)(CNtBu)2}2{μ-(η5-C5H3)2(SiMe2)2}]
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