Synthesis of a model system for the preparation of phloroglucinol containing natural products

被引:32
|
作者
Kraus, GA [1 ]
Dneprovskaia, E [1 ]
Nguyen, TH [1 ]
Jeon, I [1 ]
机构
[1] Iowa State Univ, Dept Chem, Ames, IA 50011 USA
关键词
beta-diketone; phloroglucinol; hyperforin;
D O I
10.1016/j.tet.2003.03.001
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A model system for the synthesis of phloroglucinol containing natural products was synthesized. Key steps include a manganic acetate-mediated cyclization and the facile conversion of an alkene into a beta-bromoenone. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码:8975 / 8978
页数:4
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