On the basis of introducing university library human resource management status, the significance and function of library management with the participation of university student volunteers were discussed in this paper. On the premise of reducing students economic burden, the pressure of library staff was relieved, the overall quality of staff was improved, the vigor and vitality of libray were brought. The approach of library working with the participation of student volunteers by gratuitous practice and part-time job was illustrated. The experience of library working with the participation of student volunteers was introduced. The measures include pre-post training, strengthening management and reasonable arrangement and so on. At last, the bridge and link between readers and staff were formed with the participation of university student volunteers, it is beneficial to further development of library work.