Synthesis and Characterization of Poly(ether sulfone)-graft-polydimethylsiloxane Copolymers

被引：6
|
作者：
Chen, Zheng [1 ]
Yang, Jinsheng [1 ]
Guan, Shaowei [1 ]
Li, Xiujie [1 ]
Rong, Changru [1 ]
Jiang, Zhenhua [1 ]
机构：
[1] Jilin Univ, Alan G MacDiarmid Lab, Coll Chem, Changchun 130023, Peoples R China
来源：
JOURNAL OF APPLIED POLYMER SCIENCE | 2010年 / 118卷 / 04期
关键词：
graft copolymers; poly(ether sulfones); poly-siloxanes; surfaces; MODIFIED EPOXY-RESIN; PHASE-STRUCTURE; POLYDIMETHYLSILOXANE; MORPHOLOGY; TOUGHNESS; BLOCK;
D O I：
10.1002/app.32272
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Novel poly(arylene ether sulfone) (PAES) polymers containing polydimethylsiloxane (PDMS) side chains were synthesized and characterized with NMR and Fourier transform infrared spectroscopy. The thermal properties of the copolymers were evaluated with differential scanning calorimetry and thermogravimetric analysis. The polymers showed perfect thermal stability, as the decomposition temperatures were all above 380 degrees C, and exhibited glass-transition temperatures in the range 130-188 degrees C. Furthermore, the surface properties of the copolymers were evaluated by X-ray photoelectron spectroscopy and contact angle analysis. The results show that the hydrophobic abilities of the graft copolymer surfaces were improved significantly compared to PAES through the introduction of the PDMS chains. (C) 2010 Wiley Periodicals, Inc. J Appl Polym Sci 118: 2434-2441, 2010
引用
收藏
页码：2434 / 2441
页数：8
相关论文
共 50 条
  • [1] COMPOSITIONAL DISTRIBUTION CHARACTERIZATION OF POLY(METHYL METHACRYLATE)-GRAFT-POLYDIMETHYLSILOXANE COPOLYMERS
    SCHUNK, TC
    LONG, TE
    [J]. JOURNAL OF CHROMATOGRAPHY A, 1995, 692 (1-2) : 221 - 232
  • [2] Synthesis and characterization of poly(ether sulfone) and poly(ether sulfone ketone) copolymers
    Rao, VL
    Sabeena, PU
    Rao, MR
    Ninan, KN
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 1999, 73 (11) : 2113 - 2121
  • [3] Synthesis and characterization of poly(ether sulfone) copolymers
    Rao, VL
    Rao, MR
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 1998, 69 (04) : 743 - 750
  • [4] Synthesis and characterization of hexafluoroisopropylidene bisphenol poly(arylene ether sulfone) and polydimethylsiloxane segmented block copolymers
    Cureton, LaShonda T.
    Beyer, Frederick L.
    Turner, S. Richard
    [J]. POLYMER, 2010, 51 (08) : 1679 - 1686
  • [5] Synthesis and characterization of poly(aryl ether sulfone ether ketone) copolymers
    Zhong, Ming
    Dai, Run-Ying
    Song, Cai-Sheng
    Huang, Hong
    Xu, Ling
    [J]. Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering, 2009, 25 (03): : 32 - 34
  • [6] SYNTHESIS AND CHARACTERIZATION OF POLY(ARYL ETHER KETONE SULFONE) COPOLYMERS
    WU, SD
    HEDRICK, JL
    CARTER, BK
    MOHANTY, DK
    YILGOR, E
    WILKES, GL
    MCGRATH, JE
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1985, 190 (SEP): : 98 - POY
  • [7] Synthesis and characterization of poly(phthalazinone ether nitrile)-polydimethylsiloxane block copolymers
    Dong Liming
    Liao Gongxiong
    Liu Cheng
    Wang Mingjing
    Jian Xigao
    [J]. ACTA POLYMERICA SINICA, 2008, (09) : 887 - 892
  • [8] Synthesis and characterization of novel copolymers of poly(ether ketone ketone) and poly(ether ketone sulfone imide)
    Bin Huang
    Shaojuan Cheng
    Qin Xi
    Mingzhong Cai
    [J]. Polymer Bulletin, 2012, 69 : 661 - 673
  • [9] Synthesis and characterization of poly(ether ketone) poly(ether sulfone) alternating and sequential copolymers by electrophilic reactions
    Finocchiaro, P
    Montaudo, G
    Mertoli, P
    Puglisi, C
    Samperi, F
    [J]. MACROMOLECULAR CHEMISTRY AND PHYSICS, 1996, 197 (03) : 1007 - 1019
  • [10] Synthesis and characterization of novel copolymers of poly(ether ketone ketone) and poly(ether ketone sulfone imide)
    Huang, Bin
    Cheng, Shaojuan
    Xi, Qin
    Cai, Mingzhong
    [J]. POLYMER BULLETIN, 2012, 69 (06) : 661 - 673
12345